SODIUM SILICATE ACTIVATED SLAG-FLY ASH CEMENT
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Title SODIUM SILICATE ACTIVATED SLAG-FLY ASH CEMENT
Creator JAN PIETER VERMEULEN and NATALIE LLOYD
Publisher ISEC Press
Publication Year 2557
Keyword Alkali-activated cement, Workability, Binder, Activator solids ratio, Blast-furnace slag, Compressive strength.
Abstract This research examines an alternative binder, Alkali Activated Cement (AAC), examining the fresh and hardened mechanical properties of twelve AAC mortar mixes with varying mixture proportions of blast-furnace slag, fly ash, sodium silicate (the alkali activator), and additional water. In addition to the Slag-Fly Ash mortars, nine mixtures with blast-furnace slag, silica fume, aluminum hydrate, sodium silicate, and water were tested. For all mortars, the compressive strength was exponentially related to the water/activator-solids ratio. Mortar strengths at 28 days ranged from 5 MPa to 20 MPa. Increasing the slag to binder-solids ratio from 0.1 to 0.2 increased the strength with water to binder ratios from 0.2 to 0.4. However, rapid or almost instantaneous setting times were observed for a slag to binder-solids ratio of 0.2. The research concluded that using a carefully chosen mix design can prevent quick setting while still achieving high strength and acceptable workability. It is suggested the CaO to binder-solids ratio remain below 0.07; a sodium silicate to binder solids ratio of around 0.25 is optimal; a water to binder-solids ratio should be around 0.3. When replacing fly ash, a Si/Al ratio above 2 is recommended. This research concluded that other solids (Silica Fume and Aluminum Hydrate) could replace Slag and/or Fly Ash if the overall chemical balance of the system is maintained.
ISBN 978-0-9960437-0-0
International Struct Eng and Constructn Society

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